I don't know if you’re interested or not dude but the oxide pigments thing that I mentioned in my earlier post worked really well. This method is usually just the coloring and texturing process used when making fake rock (concrete and polyurethane). It's easy and everything you need, can be bought at any decent hardware store for under $25. You end up with an even, thin shell that’s hard but still flexible, lightweight and waterproof. You just sprinkle the powder over your fake rock and tamp it down with a paintbrush and Bonding/Sealing agent. The companies that use this coloring method guarantee that the finish will last for 10yrs. It would easily stand up to snakes and even medium sized lizards.
Here’s a close up. Don’t mind the colors you can re-color it any time you want.
Edit: Most of this offgas talk comes from like 10yrs ago. Todays modern materials are much safer to use, it is illegal to make materials that throw off VOC's like they did in the past.
Icefire: The pigment method will work for you. If you need an in-depth explanation of the process just post.